4D Printing of Self‐Immolative Polymers

Johannes Markhart, Philipp Mainik, Pia S. Klee, Eva Blasco · Wiley · 2025

This study introduces self-immolative polymers for 4D printing, enabling dynamic material transformations in response to stimuli.

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Plain English summary

The research presents a new method for 4D printing using self-immolative polymers that can change shape and properties over time. These polymers can completely break down when exposed to certain stimuli, allowing for unique transformations in the printed objects.

Why this matters

This work addresses the limitations of current 4D printing technologies, such as slow response times and limited reversibility. By enabling rapid changes in material properties, it opens up new possibilities for adaptive structures in various applications.

Key findings

  • Integration of self-immolative polymers with light-based 3D printing.
  • Polymers undergo complete depolymerization in response to external stimuli.
  • Significant degrowth of objects with modulated mechanical stiffness and optical transparency.
  • Subsequent repolymerization allows for regrowth of the objects.
  • Establishes a platform for future development of dynamic, reconfigurable systems.

What's new

The introduction of self-immolative polymers for 4D printing that allows for dynamic degrowth and regrowth of structures.

Limitations

The abstract does not provide details on the practical applications or the specific external stimuli used beyond fluoride ions.

Commercial context

The technology is still in the conceptual stage and has not yet been demonstrated in practical applications.

Publication

Publisher
Wiley
Publication date
November 2, 2025
Research type
Paper
License
http://creativecommons.org/licenses/by/4.0/

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Method note: Summaries and ratings on this page are generated by AI from the abstract only. Read the original paper for full context. · Model: gpt-4o-mini-2024-07-18